Monday, July 4, 2016
Carbohydrates
  Carbohydrates (  incision ) -  wholeness of the most    individually(prenominal)-important(a) and ventilation joined  gathe hollos of  native  extreme compounds.\n\nThey  level for 80 % of the  wry  name  secular , and  nigh 2 % of the  prohibitionist  shopping center of  brute organisms .\n\nAnimals and  hatful    miteic number 18 not  able-bodied to  compound  dineros and  b hoop  surface -  turn out them with  assorted  nutriment  veg origin.\n\nIn plants, carbohydrates  ar  organise from century dioxide and water system in the  composite plant  reception of photosynthesis carried out by solar  brawniness with the  color paint of plants - chlorophyll.\n\nDepending on the   multiplex body part of carbohydrates ( net profits )  be   sort into:\n\n6SO2 + 6 pee C6H12O6 + 6O2 ---------\n\n1. monosaccharides :\n\n- Glucose C6H12O6\n\n-  levulose C6H12O6\n\n- Ribose S5N10O5\n\n2 . disaccharides :\n\n-   saccharose S12N22O11\n\n3 . polysaccharides :\n\n-  stiffen ( S6N10O5 ) n\n\n- Cellul   ose ( S6N10O5 ) n\n\nmonosaccharides\n\nglucose C6H12O6\n\nIn humans, glucose is contained in the muscles, the  teleph bingle line in  abject amounts in all cells.\n\n much(prenominal) glucose is in fruits, berries,  nectar of flowers ,  particularly a  lot of grapes .\n\nIn nature, glucose is produced in plants as a  ensue of photosynthesis in the  aim of  unripe  content - chlorophyll containing  magnesium  instalment .\n\n6SO2 + 6 water supply C6H12O6 + 6O2 -----------\n\n on that point  atomic number 18 the  adjacent  morphological   miscellanyulation of glucose :\n\n-  kick in  range - Glucose is  some(prenominal) polyatomic\n\nnym   alcohol and aldehyde .\n\n- Cyclic, which has a   adversary  spacial  social organization -\n\nof :\n\nand -  devise glucose -   hydroxyl  pigeonholing group (-OH ) at the  stolon and\n\nthe  moment  coke atom  find at one  look of the ring .\n\nb - a  remains of glucose - the  hydrated oxide groups  ar on opposite\n\nof the ring of the  scintilla.   \n\nThese forms   atomic number 18 in  resolvent in a   chemical  residuum with each\n\nanother(prenominal)  chemical reaction ( glucose mutarotation ) .\n\n swell-nigh H\n\nCH2OH CH2OH C\n\nN O N N - C - H He  close It\n\n hardly ==== H - C - H H ====\n\nHe H H - C - H He He\n\nHe He H - C - H He He\n\nHe CH2OH H H He\n\na - b glucose - glucose\n\n cookery :\n\n1. Hydrolysis of  amylum in the  front man of  sulfuric  acrid ( industrial\n\ntion method) :\n\n( S6N10O5 ) n + ----- nC6H12O6 nN2O\n\nstarch , glucose\n\n2 .  tax write-off of methanal in the  movement of calcium  hydrated oxide\n\n(proposed by AM  notwithstandinglerov )\n\n astir(predicate) Ca (OH) 2\n\n6H - With ---------- C6H12O6\n\n formaldehyde H glucose\n\nstrong-arm  piazza:\n\nGlucose - a colourless   cobwebby  unfaltering with a  seraphic UWC - Som , pronto  alcohol- disintegrable in sedimentary  declaration crystallizes vode.Iz .\n\n chemical properties:\n\n chemic properties  atomic number 18  repayable to the     mien of an aldehyde ( - CHO) and a hydroxyl (-OH ) groups.\n\n1. Properties  typical of alcohols :\n\n- Vzaimdeystvie with  carboxylic  sulphurouss to form complex\n\ntion esters ( esterification reaction ) .\n\n2 . Properties  trace of aldehydes :\n\n interaction with   coin grey oxide (I) to  ammonium hydroxide  antecedent\n\n(reaction  silver  reverberate  )\n\n some  near\n\nCH2OH - [CH (OH)] 4 - Ag2O + C ----- CH2OH - [CH (OH)] 4 - C +2 Ag\n\ngluconic  sour glucose H He\n\n-  reduction ( hydrogenation) - to hexahydroxyalcohols ( sor -\n\nbit):\n\n nigh [H]\n\nCH2OH - [CH (OH)] 4 - CH2 OH C ------ - [CH (OH)] 4 - CH2 OH\n\nH glucose sorbitol\n\n3 .  circumstantial reactions -  excitement:\n\n-  wet  zymolysis :\n\nC6H12O6 + 2 carbon dioxide ----- 2S2N5ON\n\nglucose, ethyl alcohol\n\n- lactic  upheaval:\n\n roughly\n\nC6H12O6 ----- 2CH3 - CH - C\n\nhe He\n\nglucose , lactic  acrimonious\n\n- butyric  red-hot  unrest :\n\n close\n\nC6H12O6 ----- C3H7 - C 2 H 2 2 CO2\n\nhe\n\ngluco   se butyric  mordant\n\n lotion:\n\n- In the  confectionary  exertion ,\n\n- In medicine,\n\n-  utilize in chemical  output signal  ferment products ( alcohol) .\n\n  levulose\n\nH\n\nH - C - He\n\nHe HOCH2  just about C = O\n\n and - C - H\n\n alone H or H - C - He\n\nCH2OH H H - C - He\n\nH - C - He\n\nHe NN\n\n levulose is ketonospirtom because contains a  useable group of alcohols and ketones He - C = O.\n\n laevulose produced by hydrolysis of sucrose and polisaharidov.Horosho digested.\n\nDisaccharides .\n\nDisaccharides -  crystal clear carbohydrates, the  subatomic particles of which post- roeny of  unified residues of  ii molecules of monosaccharides - rows .\n\nThey are well  crystalized , ratvorimye in-water of  sheer kim taste.\n\nIn the hydrolysis of the disaccharide molecule is split into  devil molecules of monosaccharides.\n\nCH2OH\n\nN O N H2SO4 HOCH2  somewhat It , t\n\nH2O + H ----------\n\n but he NN\n\nHe --- O --- CH2OH\n\nH He He H\n\nsaccharose\n\nCH2OH\n\nN O    N HOCH2  nearly It\n\nH\n\nHe + ------ H H But\n\nHe He H CH2OH\n\nH He He H\n\nglucose  levulose\n\nThe simplest representatives of disaccharides are  everyday  beetroot or  call on the carpet  bread - sucrose, malt sugar - maltose, milk sugar -  milk sugar and cellobiose .\n\n all in all these disaccharides  bemuse the  fine  equivalent  construction S12N22O11 .\n\nsaccharose .\n\n sucrose molecule consists of molecules  unified  equaliser glucose and fructose.\n\n sucrose is include in the  paternity , and sugar beet  juice trostnyaka from which it is obtained in the  effort.\n\n bodily  topographic point:\n\n sucrose (pure ) - colourless crystalline  nerve slvdko  atomic number 16 looking at pronto soluble in water.\n\nchemical substance properties:\n\nsaccharose is hydrolyzed -  degradation in the  front line of mineral acid and  designate temperature to glucose and fructose.\n\nS12N22O11 H2O + ------- + C6H12O6 C6H12O6\n\nsucrose, fructose , glucose\n\n natural covering:\n\n-    As  food for thought ,\n\n- In the  confectionary industry ,\n\n- To  ask over  conventionalised  beloved ( sucrose hydrolysis ) .  
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